Well I can't understand much of what was said here but you can't forward the same port to 2 different computers. If you can set the application's port to be something else and then port forward it to the computer, then we're in business.
If you're talking about a computer entirely not working on the router, probably because your IP address is the same as another device (or computer), OR you are not on the same network:
For Class C (standard for local area networks), you can set from say, 192.168.1.1 - 192.168.1.254
NETWORK PORTION: 192.168.1 - 192.168.1
HOST PORTION: .1 - .254
Also for example, say you have 2 IP addresses inside your local area network.
PORT: 30
|
|¯|---------- _________
¯ | | |
| | | |
192.168.1.2 |-----?-----| ROUTER |
192.168.1.3 | | |
| | |_________|
|¯|-----------
¯
|
PORT: 30
Well that little ASCII image didn't work out for me.