Hah, I just started using Java too...'tis all good!
scan.nextLine(), in your program, is actually just skipping the line, as what it's doing is:
scan.nextInt() gets the integer
scan.nextLine() captures all data until it hits a newline character, returning anything it found
->theoretically nextLine() is unreachable in terms of capturing data, as nextInt() would either get the int, or throw an type mismatch exception
Bottom line...try replacing it with
System.out.println();
! That should work dandy.
Also, if you didn't know, there's also System.out.print(); which is exactly the same as println except it doesn't print the newline (\n) character. So if you wanted to have it like:
Please enter the number of employees: 1
Please enter employee #1: Jenny
Enter their extension number: 4578
You'd do something like
System.out.print("Please enter the number of employees: ");
int number = scan.nextInt( );
System.out.println( );
.
.
System.out.print("Please enter employee #1");
String employeescan.nextLine( );
etc. By the by, I'm very surprised you made any sense of it... as I am terrible at explaining these things...